The Syrian government has been urged to allow UN inspectors to visit the site where it is claimed more than 1,300 people died in a chemical weapons attack.
The National Coalition claims toxic gas was used by President Bashar al Assad's forces during a bombardment of rebel-held areas outside Damascus.
Government officials said the claims were "totally false" and the international news organisations reporting them were "implicated in the shedding of Syrian blood and support terrorism".
The incident comes just days after a 20-strong team of UN weapons inspectors arrived in the capital to investigate whether chemical weapons have been used in the conflict.
The attacks are alleged to have taken place in Ein Tarma and Zamalka And following an emergency meeting of the UN Security Council, Deputy Secretary-General Jan Eliasson, said: "We very much hope that we will be able to conduct the investigation.
"Dr Sellstrom and his team are in place in Damascus. We hope that they will be given access to the area by the government - it's a requirement of consent in situations like this.
"And that also the security situation will allow them to enter the area.
"The Secretary-General has already expressed his preparedness to conduct the investigation.
"We are in contact with the Syrian government - we hope that all other parties will co-operate so that we conduct the investigation and we hope that everybody realises the importance of ceasing hostilities."
British Foreign Secretary William Hague urged international supporters of the Syrian regime to "wake up to...its murderous and barbaric nature" ahead of the UN meeting.
However Russia, which has supported the regime and vetoed past attempts to secure a tough UN resolution, suggested it could be a "premeditated provocation" by opposition forces.
Officials from Russia and China are reported to have blocked a stronger press statement supported by Britain, France, the US and others.
Earlier, Mr Hague said that if verified, the attack "would mark a shocking escalation in the use of chemical weapons in Syria".
He added: "Those who order the use of chemical weapons, and those who use them, should be in no doubt that we will work in every way we can to hold them to account."
Unverified footage of casualties, including children, in makeshift hospitals suffering convulsions and breathing difficulties was circulated on YouTube.
Syria is thought to have some of the world's largest stocks of chemical weapons, including mustard gas and the nerve agent sarin, but the government in Damascus refuses to confirm this is the case.
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